1. Oxidative passivation
Features: The passivation film formed on the metal surface is mainly composed of oxides. The passivation film has high chemical stability and corrosion resistance, and can effectively prevent corrosive media such as oxygen and water from contacting the metal matrix.
Application: Widely used in steel, stainless steel and other metal passivation treatment. For example, the oxide film naturally formed in the air of steel and the passivation film of iron oxide formed by chemical treatment are both oxidized passivation.
2. Precipitation passivation
Features: The passivation film is formed by the precipitation of insoluble compounds generated by the reaction of the metal surface with ions in the solution. The corrosion resistance of precipitation-type passivation film depends on the stability and densification of precipitation.
Application: It is often used for passivation treatment of copper, zinc and other metals. For example, when copper is passivated in a solution containing chromates, a precipitation-type passivating film composed of compounds such as copper chromate is formed on the surface.
3. Adsorption passivation
Features: The passivation film is formed by organic or inorganic molecules adsorbed on the surface of the metal. The thickness of the adsorption passivation film is thin, but it can effectively prevent the erosion of corrosive media.
Application: In some special environments, such as high temperature, high pressure, strong corrosive media, adsorption passivation can be used as an auxiliary anti-corrosion means. For example, in the petrochemical industry, some metal equipment will adsorb a layer of organic corrosion inhibitor molecules on the surface to form an adsorption-type passivation film.